In the heat treatment process, quenching and tempering is very important for casting grinding mill balls. It influences the balls hardness, inner structure, impack value. These are used to indicate a balls quality. Here briefly introduce you the  what is the quenching and tempering. 

Quenching

Quenching is a process of cooling a metal at a rapid rate. This is most often done to produce a martensite transformation. In ferrous alloys, this will often produce a harder metal, while non-ferrous alloys will usually become softer than normal.

To harden by quenching, a metal (usually steel or cast iron) must be heated above the upper critical temperature and then quickly cooled. Depending on the alloy and other considerations (such as concern for maximum hardness vs. cracking and distortion), cooling may be done with forced air or other gases, (such as nitrogen). Liquids may be used, due to their better thermal conductivity, such as oil, water, a polymer dissolved in water, or a brine. Upon being rapidly cooled, a portion of austenite (dependent on alloy composition) will transform to martensite, a hard, brittle crystalline structure. The quenched hardness of a metal depends on its chemical composition and quenching method. Cooling speeds, from fastest to slowest, go from brine, polymer (i.e. mixtures of water + glycol polymers), fresh water, oil, and forced air. However, quenching a certain steel too fast can result in cracking, which is why high-tensile steels such as AISI 4140 should be quenched in oil, tool steels such as ISO 1.2767 or H13 hot work tool steel should be quenched in forced air, and low alloy or medium-tensile steels such as XK1320 or AISI 1040 should be quenched in brine.

Some Beta titanium based alloys have also shown similar trends of increased strength through rapid cooling. However, most non-ferrous metals, like alloys of copper, aluminum, or nickel, and some high alloy steels such as austenitic stainless steel (304, 316), produce an opposite effect when these are quenched: they soften. Austenitic stainless steels must be quenched to become fully corrosion resistant, as they work-harden significantly.

For casting grinding mill balls, we usually adopt oil and air quenching two methods. For super high chrome balls, air quenching is welcomed. The heating temperature in the heat treatment machine, quench oil temperature, quenching time are vital. Little change will have a big difference for balls. So if you want to get a qualified balls, pay more attention on quenching. 

Tempering

Untempered martensitic steel, while very hard, is too brittle to be useful for most applications. A method for alleviating this problem is called tempering. Most applications require that quenched parts be tempered. Tempering consists of heating steel below the lower critical temperature, (often from 400 to 1105 ˚F or 205 to 595 ˚C, depending on the desired results), to impart some toughness. Higher tempering temperatures (may be up to 1,300 ˚F or 700 ˚C, depending on the alloy and application) are sometimes used to impart further ductility, although some yield strength is lost.

Tempering may also be performed on normalized steels. Other methods of tempering consist of quenching to a specific temperature, which is above the martensite start temperature, and then holding it there until pure bainite can form or internal stresses can be relieved. These include austempering and martempering.

For casting grinding mill balls, usually for big size of the low chrome balls and quenched high chrome balls, we all need to do tempering process. Heating temperature and time are the key point. 

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